Direct observation of dangling bond motion in disordered silicon

نویسندگان

  • N. H. Nickel
  • E. A. Schiff
چکیده

We report an unexpected temperature dependence of the electron-spin-resonance linewidth DHPP for the silicon D-center resonance in polycrystalline silicon. Distinct temperature dependences were found in asprepared and hydrogen-passivated polycrystalline silicon. This observation invalidates the identification of this resonance with a static dangling bond, and changes the perspective on similar D-center resonances observed in amorphous silicon, porous silicon, and at crystal silicon interfaces. We propose that motional averaging is the principal mechanism for this effect, and illustrate this view with a calculation based on hopping of the D center. @S0163-1829~98!01723-8#

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تاریخ انتشار 1998